The Greek adverbs derive from the adjectives.
adjective stem + -α or -ως ending
The comparative is formed by the ending -ότερα or by the word πιο located before the adverb.
Exceptions: καλός – πιο καλά / καλύτερα (better) πολύς – πιο πολύ / περισσότερα (more)
Besides there are numerous adverbs with adverbial phrases which are not directly derived by/from an adjective.